Synthesis of Arylhydrazines by Reaction of Arylbromides with DEAD via Sonochemical Barbier Reaction |
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| Authors: | Adam Shih‐Yuan Lee Ching‐Hui Chung Shu‐Fang Chu Yu‐Ting Chang |
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| Institution: | Department of Chemistry, Tamkang University, Tamsui 251, Taipei, Taiwan, R. O. C. |
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| Abstract: | A series of arylhydrazines was synthesized from the reaction mixture of Mg powder, 1,2‐dibromoethane, aryl bromide and DEAD (diethyl azodicarboxylate) in THF under ultrasound. This sonochemical Barbier reaction provides an efficient and inexpensive preparation method for synthesis of arylhydrazines. |
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| Keywords: | Arylhydrazine Sonochemical Barbier reaction Diethyl azodicarboxylate |
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