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新型侧链高分子液晶单体的合成
引用本文:魏秀贞,耿同谋.新型侧链高分子液晶单体的合成[J].有机化学,1993,13(3):272-276.
作者姓名:魏秀贞  耿同谋
作者单位:北京理工大学化工与材料学院,北京理工大学化工与材料学院 北京,100081,北京,100081 现在河南水利科学研究所工作。
摘    要:为GC作为固定液的目的,首次合成了四种新的端基为异硫氰基的芳酯类液晶单体(MLC;Mesomorphic liquid crystal).将其接到聚硅氧烷主链上可期望得到性能优良的侧链高分子液晶.

关 键 词:气相色谱  液晶  固定相  羧酸酯  聚硅氧烷  芳香族羧酸  异硫氰酸酯  介晶态

Synthesis of monomers of new type side chain polymeric liquid crystal
WEI Xiu-Zhen,GENG Tong-Mou Chemical Engineering and Material College,Beijing Institute of Technology, Beijing.Synthesis of monomers of new type side chain polymeric liquid crystal[J].Chinese Journal of Organic Chemistry,1993,13(3):272-276.
Authors:WEI Xiu-Zhen  GENG Tong-Mou Chemical Engineering and Material College  Beijing Institute of Technology  Beijing
Institution:WEI Xiu-Zhen,GENG Tong-Mou Chemical Engineering and Material College,Beijing Institute of Technology,100081 Beijing
Abstract:A new type of monomeric liquid crystal with isothiocyano(--NCS)terminal group was pre-pared. The product characterization was carried out by IR. DSC, hot-stage polarization microscopeand elemental analysis. The results showed that these monomers with isothiocyano group have a widerange mesomorphicstate and high thermal stability. This study laid a foundation for the preparation ofnovol side chain polymeric liquid crystal.
Keywords:Side chain polymeric liquid crystal  isothiocyano group  mesomorphic state
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