| 纤维素类手性固定相及高效液相色谱-旋光仪联用技术的研究 |
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| 引用本文： | 张欣,高连勋. 纤维素类手性固定相及高效液相色谱-旋光仪联用技术的研究[J]. 分析化学, 2001, 29(5): 526-529 |
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| 作者姓名： | 张欣 高连勋 |
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| 作者单位： | 中国科学院长春应用化学研究所, |
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| 摘 要： | 合成了3种纤维素衍生物并分别填充分析型色谱柱，研究了不同的涂敷条件对柱效的影响以及色谱柱的稳定性，对外消旋化合物进行了手性拆分。实现了高效液相色谱－旋光仪的联用，获得了在线旋光曲线。
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| 关 键 词： | 手性固定相 高效液相色谱－旋光仪联用 外消旋化合物 柱效 纤维素 色谱柱 手性拆分 |
The Research of Cellulose Derivatives as Chiral Stationary Phases and High Performance Liquid Chromatography with Polarimeter as On-line Detector |
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| Zhang Xin,GAO Lianxun. The Research of Cellulose Derivatives as Chiral Stationary Phases and High Performance Liquid Chromatography with Polarimeter as On-line Detector[J]. Chinese Journal of Analytical Chemistry, 2001, 29(5): 526-529 |
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| Authors: | Zhang Xin GAO Lianxun |
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| Abstract: | Three cellulose derivatives were synthesized and used as chiral stationary phases based on silica gel. The effects of adsorbances on the column numbers and stabilities have been investigated. These stationary phases exhibited high chiral recognition for various racemates. At the same time, the on line curves of polarimeter were obtained by high performance liquid chromatography with polarimeter as on line detector. |
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| Keywords: | Chiral stationary phase cellulose derivatives resolution high performance liquid chromatography polarimetry |
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