Imitating micelles as a way to control coordination self-assembly: cage-polymer switching directed rationally by solvent polarity or pH |
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| Authors: | Giri Nicola James Stuart L |
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| Institution: | Centre for the Theory and Application of Catalysis, School of Chemistry and Chemical Engineering, Queen's University Belfast, David Keir Building, Stranmillis Road, Belfast BT9 5AG, UK. |
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| Abstract: | Disguising a metal complex as a micelle by using amphiphilic phosphine ligands enables it to switch between a coordination polymer and a discrete cage in response to solvent polarity or pH; this medium-dependent behaviour of the complex is rational because it parallels that of true micelles. |
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