Stereoselective palladium-catalyzed allylic alkylations of peptide amide enolates |
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| Authors: | Datta Swarup Kazmaier Uli |
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| Institution: | Institut für Organische Chemie, Universit?t des Saarlandes, D-66123, Saarbrücken, Germany. |
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| Abstract: | Pd-catalyzed allylations are an excellent tool for stereoselective peptide modifications, being clearly superior to normal alkylations. The reactions proceed not only in high yield, but also high regio- and diastereoselectivities, and trans-products are formed exclusively. Therefore, this is a powerful synthetic tool for natural product and drug synthesis. |
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