| Solvothermal Synthesis, Crystal Structure and Electrochemical Property of Complex [Co(p-MBA)2(2,2'-bipy)(H2O)]·(H2O) |
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| 作者单位： | YANG Ying-Qun（Department of Chemistry and Materials Science,Hengyang Normal University, Hengyang 421008, China） ;LI Chang-Hong（Department of Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China） ;LI Wei（Department of Chemistry and Materials Science,Hengyang Normal University, Hengyang 421008, China） ;KUANG Yun-Fei（Department of Chemistry and Materials Science,Hengyang Normal University, Hengyang 421008, China） ; |
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| 基金项目： | Supported by the Construct Program of the Key Discipline in Hunan Province and the Foundation of Education Committee of Hunan Province (06C195) |
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| 摘 要： | One novel complex [Co(p-MBA)2(2,2'-bipy)(H2O)]·(H2O) has been synthesized by the reaction of p-methylbenzoic acid with 2,2'-bipyridine in the solvent mixture of water and methanol. It crystallizes in triclinic, space group P-1 with a=0.70479(14), b=1.1211(2), c=1.6718(3) nm, α=103.806(3), β=90.795(3), γ=104.207(3)°, V=1.2399(4) nm3, Mr=512.41, Dc=1.373 g/cm3, Z=2, F(000)=532, μ=0.733 mm-1, R=0.0432 and wR=0.0957. The crystal structural analysis shows that the cobalt atom is coordinated with three oxygen atoms from two p-methylbenzoic acids and one water molecule and two nitrogen atoms from one 2,2'-bipyridine,forming a distorted square-pyramidal coordination geometry. The cyclic voltammetry behavior of the complex is also reported.
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| 关 键 词： | cobalt(Ⅱ) complex solvothermal synthesis electrochemical property |
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