| Synthesis and Crystal Structure of［（n－Bu）_4N］_2［Mo_4O_（10）（OC_（10）H_6O）_2（OCH_3）_2］ |
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| 引用本文： | Lu Xiao-Ming, Zhu Hui-Ju, Yang Ning, Liu Shun-Cheng, Jin Xiang-Lin(Department of Chemistry,Capital Normal University,Beijing 100037) (Experiment Center,Capital Normal University,Beijing 100037)(Institute of Physical Chemistry,Peking University,Beij. Synthesis and Crystal Structure of［（n－Bu）_4N］_2［Mo_4O_（10）（OC_（10）H_6O）_2（OCH_3）_2］[J]. 结构化学, 1995, 0(2) |
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| 作者姓名： | Lu Xiao-Ming Zhu Hui-Ju Yang Ning Liu Shun-Cheng Jin Xiang-Lin(Department of Chemistry Capital Normal University Beijing 100037) (Experiment Center Capital Normal University Beijing 100037)(Institute of Physical Chemistry Peking University Beij |
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| 作者单位： | Lu Xiao-Ming; Zhu Hui-Ju; Yang Ning; Liu Shun-Cheng; Jin Xiang-Lin(Department of Chemistry，Capital Normal University，Beijing 100037) (Experiment Center，Capital Normal University，Beijing 100037)(Institute of Physical Chemistry，Peking University，Beij |
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| 摘 要： | ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ［（ｎ－Ｂｕ）_４Ｎ］_２［Ｍｏ_４Ｏ_（１０）（ＯＣ_（１０）Ｈ_６Ｏ）_２（ＯＣＨ_３）_２］￥ＬｕＸｉａｏ－Ｍｉｎｇ；ＺｈｕＨｕｉ－Ｊｕ；ＹａｎｇＮｉｎｇ；ＬｉｕＳｈｕｎ－Ｃｈｅｎｇ；ＪｉｎＸ?..
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Synthesis and Crystal Structure of[(n-Bu)_4N]_2[Mo_4O_(10) (OC_(10)H_6 O)_2 (OCH_3 )_2] |
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| Lu Xiao-Ming, Zhu Hui-Ju, Yang Ning, Liu Shun-Cheng, Jin Xiang-Lin. Synthesis and Crystal Structure of[(n-Bu)_4N]_2[Mo_4O_(10) (OC_(10)H_6 O)_2 (OCH_3 )_2][J]. Chinese Journal of Structural Chemistry, 1995, 0(2) |
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| Authors: | Lu Xiao-Ming Zhu Hui-Ju Yang Ning Liu Shun-Cheng Jin Xiang-Lin |
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| Abstract: | n-Bu )_4N]_2 [Mo_4O_(10) (OC_(10)H_6O)_2 (OCH_3 )_2 ] crystallizes in the monoclinic, space group P21/c, a= 10. 926 (6) , b= 17. 861 (7) . c= 16. 258 (7) ,β=91. 16(4)°, V= 3172 (2) ￣3, Z = 2, M_r = 1407. 0, D_c =1. 473 g/cm￣3 , μ= 0. 814mm￣(-1), F(000) = 1448. T= 298K , final R= 0. 043 and R_w= 0. 058 for 3291 observed reflections. The structure of the complex consists of two (n-Bu)_4N￣+ cations and one [Mo_4 O_(10) (OC_(10)H_6O)_2 (OCH_3 )_2]￣(2-) anion having crystallographic C_i symmetry, with a tetranuclear core of [Mo_4 O_(10)(OCH_3 )_2]￣(2+) . |
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| Keywords: | polyoxomolybdate 2 3-dihydroxynaphthalene crystal structure |
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