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(CH3)2Si(C5H4)2ZrS5: Ein verbrücktes Zirconocen-Pentasulfid-Chelat
Authors:Nikolaos Klouras
Affiliation:(1) Institut für Anorganische Chemie, Universität Patras, GR-26000 Patras, Griechenland
Abstract:Summary By reaction of the [1]zirconocenophane(CH)3)2Si(C5H4)2ZrCl2 with equivalent amounts of LiEt3BH and sulfur, (CH3)2Si(C5H4)2ZrS5 can be prepared as chelate complex. The structure of this ZrS5 chelate is discussed on the basis of its1H NMR spectrum.
Keywords:[1]Zirconocenophanes  Bridged metallocyclosulfanes  Metal-sulfur complexes
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