| 一维链状配位聚合物[Co(imbz)2(H2O)2]n[imbz=4′-(1-咪唑基亚甲基)苯甲酸根]的合成及晶体结构 |
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| 引用本文： | 邹志红,李东风,樊键,孙为银.一维链状配位聚合物[Co(imbz)2(H2O)2]n[imbz=4′-(1-咪唑基亚甲基)苯甲酸根]的合成及晶体结构[J].无机化学学报,2001,17(6):908-910. |
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| 作者姓名： | 邹志红 李东风 樊键 孙为银 |
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| 作者单位： | [1]东南大学化学化工系，南京210096 [2]南京大学配位化学研究所配位化学国家重点实验室，南京210093 |
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| 基金项目： | 国家自然科学基金资助项目(No.29971015). |
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| 摘 要： | A new coordination polymeCo (imbz)2(H2O)2]nimbz =4'-(imidazol-1-ylmethyl)benzoate anion]was synthesized and characterized by x-ray crystallography.The title complex crystallizes in monoclinic,space group P21/c,a=10.910(2),b=8.8720(18),c=11.252(2)Å,β=92.20(3)°,V=1088.3(4)Å3,Z =2,Dc=1.518g·cm-3,μ=0.836cm-1,F(000)=514,R=0.0679,wR=0.1710.Each Co(Ⅱ)atom has a distorted octahedral coordination geometry and is six-coord-inated by two water molecules and fou rimbz ligands.Each imbz ligand connects two Co(Ⅱ) to gen-erate an infinite 1Dtwisted chain structure.
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| 关 键 词： | 4‘－（1－咪唑基亚甲基）苯甲酸根 晶体结构 合成 钴配合物 一维链状配位聚合物 |
| 收稿时间： | 2001/6/18 0:00:00 |
| 修稿时间： | 2001年6月18日 |
Synthesis and Crystal Structure of a New One-Dimensional Chain Coordination Polymer[Co(imbz)2(H2O)2]n[imbz =4'-(Imidazol-1-ylmethyl)benzoate Anion] |
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| ZOU Zhi-Hong,LI Dong-Feng,FAN Jian and SUN Wei-Yin.Synthesis and Crystal Structure of a New One-Dimensional Chain Coordination Polymer[Co(imbz)2(H2O)2]n[imbz =4'-(Imidazol-1-ylmethyl)benzoate Anion][J].Chinese Journal of Inorganic Chemistry,2001,17(6):908-910. |
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| Authors: | ZOU Zhi-Hong LI Dong-Feng FAN Jian and SUN Wei-Yin |
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| Institution: | Department of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096,Coordination Chemistry institute, State Key Laboratory of Coordination chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry institute, State Key Laboratory of Coordination chemistry, Nanjing University, Nanjing 210093 and Coordination Chemistry institute, State Key Laboratory of Coordination chemistry, Nanjing University, Nanjing 210093 |
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| Abstract: | |
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| Keywords: | 4'-(imidazol-1-ylmethyl )benzoate crystal structure cobalt complex coordination polymer |
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