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Surfactant-Water Systems with Small Layer Rigidity Phase Stability, Defects Models and Defects Mobility in Polyoxyethylene Surfactant with Water
Authors:Maurice Kleman
Abstract:Starting from recent experiments in non-ionic surfactants, we discuss various topics characteristic of low rigidity K1 materials. (1) The stability of the lamellar and cubic phases is studied in a simple model involving K2 the saddle-splay constant K2, and entropy terms due to the chains. We expect the lamellar phase to have a large range of existence, and the cubic phase to be of small extent. (2) We compare to cubic phases stability in large K1 materials. We discuss the mobility of edge dislocations on the basis of a new model of the core which involves stretching of the core layers in one dimension, and easy nucleation of pores in this region. The core extension is a characteristic length of low K1 materials which is much larger than de Gennes' length for microemulsions with a similar low K1.
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