Formation of salts from acetyl- and formylpyrroles,and pyrrole ring reactivity |
| |
Authors: | Yu E Sklyar R P Evstigneeva N A Preobrazhenskii |
| |
Institution: | (1) Lomonosov Institute of Fine Chemicals Technology, Moscow |
| |
Abstract: | With 2-acetyl- and 2-formylpyrrole, salt formation is via proton addition to the carbonyl oxygen. In salt formation with pyrrole derivatives having an acetyl or formyl group at position 2, position 5 is deactivated for electrophilic substitution. With salts of 3-acetyl- and 3-formylpyrroles, position 2 is also deactivated, while position 5 is activated. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|