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Platinum‐Promoted Ga/Al2O3 as Highly Active,Selective, and Stable Catalyst for the Dehydrogenation of Propane
Authors:Jesper J. H. B. Sattler  Ines D. Gonzalez‐Jimenez  Lin Luo  Brien A. Stears  Andrzej Malek  David G. Barton  Beata A. Kilos  Mark P. Kaminsky  Tiny W. G. M. Verhoeven  Eline J. Koers  Marc Baldus  Bert M. Weckhuysen
Abstract:A novel catalyst material for the selective dehydrogenation of propane is presented. The catalyst consists of 1000 ppm Pt, 3 wt % Ga, and 0.25 wt % K supported on alumina. We observed a synergy between Ga and Pt, resulting in a highly active and stable catalyst. Additionally, we propose a bifunctional active phase, in which coordinately unsaturated Ga3+ species are the active species and where Pt functions as a promoter.
Keywords:Galliumoxid  Heterogene Katalyse  Platin  Propandehydrierung  Synergieeffekte
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