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Stable cationic diene complexes of iron |
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| Authors: | Michael J Hynes Mary F T Mahon Patrick McArdle |
| Institution: | Chemistry Department, University College, Galway Ireland |
| Abstract: | Complexes having the formula C5Me5Fe(CO)-η4-diene]+ BF4− have been prepared by reaction of C5Me5Fe(CO)2THF]+BF4− with a range of dienes. A Brönsted plot derived from the rates of addition of amine nucleophiles suggests an essentially “soft” nature for the complexes diene. |
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