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PMBP缩磺胺席夫碱及其铜配合物的合成与抑菌活性
引用本文:李东颖,俞志刚,张桂玲.PMBP缩磺胺席夫碱及其铜配合物的合成与抑菌活性[J].化学研究与应用,2009,21(3).
作者姓名:李东颖  俞志刚  张桂玲
作者单位:哈尔滨理工大学化学与环境工程学院,黑龙江,哈尔滨,150040
基金项目:国家自然科学基金,黑龙江省自然科学基金,哈尔滨市青年科学基金 
摘    要:4-酰基吡唑啉酮类化合物是一类重要的有机配体.其所具有的酮式和烯醇式异构体并存且含有多个配位原子的特性使得该类化合物在与金属离子配位时存在多种配位方式,从而形成单核、同双核、异双核和多核等金属配合物1-5].

关 键 词:席夫碱  铜配合物  合成  抑菌活性

Synthesis and antibacterial activity of the Schiff base derived from PMBP and sulfanilamide and its transitional metallic copper complex
LI Dong-ying,YU Zhi-gang,ZHANG Gui-ling.Synthesis and antibacterial activity of the Schiff base derived from PMBP and sulfanilamide and its transitional metallic copper complex[J].Chemical Research and Application,2009,21(3).
Authors:LI Dong-ying  YU Zhi-gang  ZHANG Gui-ling
Institution:Chemistry and Environmental Engineering College;Harbin University of Science and Technology;Harbin 150040;China
Abstract:In this paper,one novel Schiff base(HL) derived from 1-phenyl-3-methyl-4-benzoyl-pyrazolone-5(PMBP) and sulfanilamide and its corresponding transitional metallic copper complex have been synthesized in the nonaqueous solvent.The formula of complex is CuL2 based on elemental analysis,complexometric titration,molar conductance value and mass spectra data.Its molecular structure is characterized by means of IR,TG and 1HNMR,etc.,and the antibacterial activities under different concentrations of these two compou...
Keywords:Schiff base  copper complex  synthesis  antibacterial activity  
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