Effect of Gd2O3 on the hydrogen evolution property of nickel–cobalt coatings electrodeposited on titanium substrate |
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| Authors: | Ping He Xiaofang Yi Yongjun Ma Wei Wang Faqin Dong Licheng Du Hongtao Liu |
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| Institution: | aSchool of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, PR China;bCollege of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan, PR China |
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| Abstract: | The effect of rare earth compound, Gd2O3, on the microstructure and the hydrogen evolution property of Ni–Co alloy electrode was studied. The morphology and microstructure were characterized by SEM and XRD, respectively, and the electrocatalytic efficiency was evaluated on the basis of electrochemical data obtained from steady-state polarization curves, Tafel curves and electrochemical impedance spectroscopy measurements carried out in 0.50 M Na2SO4+0.10 M H2SO4 solution. It was found that the embedded Gd2O3 particles largely enhanced the electrocatalytic activity of Ni–Co alloy electrode to hydrogen evolution reaction. |
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| Keywords: | A Oxides A Thin films C Electron microscopy D Microstructure D Electrochemical properties |
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