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Copper(II) complex of the chelating agent EDTA bis(tyrosine)
Authors:A. E. O. Fisher  D. P. Naughton
Affiliation:(1) School of Pharmacy and Biomolecular Sciences, University of Brighton, Moulscoomb, Brighton, BN2 4GJ, UK
Abstract:The synthesis technique is given and the results of X-ray study of a copper(II) compound, Cu(O12N4C28H30)·7H2O, are reported. The structure is molecular and the copper atom is coordinated by a distorted octahedron exhibiting a Jahn-Teller effect. The Cu-O(carbonyl) bond is 0.31 Å longer than the axial carboxylate to copper bonds.
Keywords:metal ion complexes of EDTA (ethyl tyrosine)  copper  structure  Jahn-Teller effect
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