| 特大孔交联苯乙烯-二乙烯苯共聚物的制备和孔结构研究Ⅰ |
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| 引用本文： | 何炳林,张政朴,钱庭宝,陈洪彬,郭贤权,史作清,斐光文.特大孔交联苯乙烯-二乙烯苯共聚物的制备和孔结构研究Ⅰ[J].高分子学报,1982,0(4):278-283. |
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| 作者姓名： | 何炳林 张政朴 钱庭宝 陈洪彬 郭贤权 史作清 斐光文 |
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| 作者单位： | 南开大学化学系
(何炳林，张政朴，钱庭宝，陈洪彬，郭贤权，史作清)，南开大学化学系(斐光文) |
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| 摘 要： | 本文以聚乙酸乙烯酯配合其它溶剂(如乙酸乙酯、正辛醇、二氧六环等)作致孔剂,制成了一系列孔径在数万埃,孔容为1ml/g(干树脂)左右的苯乙烯-二乙烯苯系特大孔交联共聚物,并进行了部分功能基反应,制成了强碱阴离子交换树脂,还讨论了一些实验结果。
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| 收稿时间： | 1981-08-27 |
PREPARATION AND INVESTIGATION OF PORE STRUCTURE ON STYRENE-DIVINYLBENZENE COPOLYMER WITH SUPER-MACROPORES Ⅰ |
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| He Bing-lin,Zhang Zheng-pu,Qian Ting-bao,Chen Hong-bin,Guo Xian-quan,Shi Zuo-qing,Pei Guang-wen.PREPARATION AND INVESTIGATION OF PORE STRUCTURE ON STYRENE-DIVINYLBENZENE COPOLYMER WITH SUPER-MACROPORES Ⅰ[J].Acta Polymerica Sinica,1982,0(4):278-283. |
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| Authors: | He Bing-lin Zhang Zheng-pu Qian Ting-bao Chen Hong-bin Guo Xian-quan Shi Zuo-qing Pei Guang-wen |
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| Institution: | Department of Chemistry; Nanlcai University |
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| Abstract: | A series of poly (styrene-divinylbenzene) matrixes with sapermacropores have been prepared by using polyvinyl acetate together with organic solvents (e. g. ethyl acetate, n-octyl alcohol, dioxane, touene) as porogenic agents. The average pore radius of the matrix is in the range of tens of thousands Angstroms and the pore volume is about 1ml/g (dry resin). The matrixes have been partially aininated after chloromethyla-tion to impart anion exchange capacity to the resin. Kesults of these experiments are discussed. |
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