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Design of BODIPY Dyes as Photosensitisers in Multicomponent Catalyst Systems for Light‐Driven Hydrogen Production
Authors:Laura Dura  Dr Johannes Ahrens  Dr Marga‐Martina Pohl  Sebastian Höfler  Prof Dr Martin Bröring  Dr Torsten Beweries
Institution:1. Leibniz‐Institut für Katalyse e.V. an der Universit?t Rostock, Albert‐Einstein‐Str. 29a, 18059 Rostock (Germany);2. Institut für Anorganische und Analytische Chemie, TU Braunschweig, Hagenring 30, 38106 Braunschweig (Germany)
Abstract:A study of visible‐light‐driven hydrogen production using a multicomponent system consisting of different boron dipyrromethene (BODIPY) dyes, triethylamine and {Pd(PPh3)Cl2}2] from THF/water mixtures is presented. A trio of meso‐mesityl BODIPY dyes display the best activities and long‐term stabilities of more than ten days with the 2,6‐diiodo derivative showing the best performance.
Keywords:BODIPY  hydrogen  palladium  photochemistry  water
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