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A new fluorescent chemosensor for copper(II) and molecular switch controlled by light
Authors:Zhi Liang  Lin Jiang
Institution:a Lab of Organic Optoelectronic Functional Materials and Molecular Engineering, Technical Institute of Physics and Chemistry & Graduate University, Chinese Academy of Sciences, Beijing 100080, PR China
b The School of Chemistry and Chemical Engineering of Jinan University, Jinan 250022, PR China
c Department of Applied Materials, The Central Research Lab of BYD Company Limited, PR China
Abstract:A novel fluorescent chemosensor with two 5-nitro-salicylaldehyde groups at the upper rim of calix4]arene has been synthesized. The chemosensor can effectively recognize copper(II) ion. This system could be considered as a molecular switch. By alternating the light irradiation of mixed solution formed by the host and Cu2+, off-on-off fluorescent switching is carried out.
Keywords:Logic switch  Photoswitch  Calix[4]arene  Schiff bases  Molecular recognition
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