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Mercury extraction by ionic liquids: temperature and alkyl chain length effect
Authors:Raimondo Germani  Gianfranco Savelli  Nicoletta Spreti
Affiliation:a CEMIN, Centro di Eccellenza Materiali Innovativi Nanostrutturati, Dipartimento di Chimica, Università di Perugia, Perugia, Italy
b Dipartimento di Chimica, Ingegneria Chimica e Materiali, Università dell’Aquila, L’Aquila, Italy
Abstract:The preliminary results described here show the complete transfer of Hg(II) ions, in the absence of a chelating agent in 1-alkyl-3-methylimidazolium hexafluorophosphate ionic liquids; the lag time required to gain the quantitative metal ion partition turned out to be strongly dependent both on alkyl chain length on the imidazolium ring and on the working temperature.
Keywords:Ionic liquids   Mercury ions extraction   Biphasic system   Temperature effect
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