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Efficient and convenient oxidation of organic halides to carbonyl compounds by H2O2 in ethanol
Authors:Jingting Tang
Affiliation:Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215123, China
Abstract:Various primary and secondary organic bromides were oxidized by hydrogen peroxide in refluxing ethanol to give the corresponding aldehydes/and ketones in high yield up to 94%; organic chlorides were oxidized to the corresponding aldehydes/and ketones by the same oxidant in ethanol in the presence of 10 mol % of KBr as the catalyst.
Keywords:Oxidation   Organic halide   Hydrogen peroxide   Aldehyde   Ketone
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