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Reaction of unsymmetrical trifluoromethyl-containing 1,3-dicarbonyl compounds with ‘push-pull’ enamines
Authors:Dmitriy A. Sibgatulin
Affiliation:Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Murmanska 5, Kyiv-94, 02094, Ukraine
Abstract:The reaction of ‘push-pull’ enamines with trifluoromethyl-containing 1,3-dicarbonyl compounds was investigated. It was found that the reaction is sensitive both to the structure of the enamines and to reaction conditions. As a result, a set of various trifluoromethyldialkylanilines was obtained.
Keywords:4,4,4-Trifluoroacetoacetate   &lsquo  Push-pull&rsquo   enamines   Trifluoromethylated benzenes   Cyclocondensation
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