Total synthesis of (−)-martinellic acid |
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| Authors: | Vivek Badarinarayana |
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| Affiliation: | Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, TX 76019, United States |
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| Abstract: | An enantioselective formal total synthesis of the pyrrolo[3,2-c]quinoline natural product martinellic acid has been achieved. The key steps involve a Pd-catalyzed aryl amidation reaction of a pyrroglutamate derivative, an intramolecular [3+2] azomethine ylide-alkene cycloaddition and a reductive ring opening reaction. |
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