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Enzyme promiscuity: first protein-catalyzed Morita-Baylis-Hillman reaction |
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| Authors: | Manfred T Reetz Régis Mondière José Daniel Carballeira |
| Institution: | Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, D-45470 Mülheim /Ruhr, Germany |
| Abstract: | The Morita-Baylis-Hillman reaction of cyclohexenone and p-nitro benzaldehyde is catalyzed by carrier proteins such as serum albumins or enzymes such as certain lipases, conversion of up to 35% and enantioselectivities of up to 19% being observed. |
| Keywords: | Baylis-Hillman reactions Enzymes and enzyme reactions Proteins Asymmetric reactions Enantioselection |
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