gem-Difluoropropargylation of aldehydes using cat. In/Zn in aqueous media |
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| Authors: | Satoru Arimitsu |
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| Institution: | Department of Chemistry, University of Louisville, Louisville, KY 40292, USA |
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| Abstract: | Zn (0.9 equiv) in combination with catalytic amounts of In (0.1 equiv) and I2 (0.1 equiv) was found to effect the reaction of several difluoropropargyl bromide derivatives with aldehydes to produce gem-difluorohomopropargyl alcohols in aqueous media under conditions suitable for large scale applications. |
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| Keywords: | Cat indium Zinc Aqueous media gem-Difluorohomopropargyl alcohols |
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