| A novel,green 1-glycyl-3-methyl imidazolium chloride-copper(Ⅱ) complex catalyzed C-H oxidation of alkyl benzene and cyclohexane |
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| 作者姓名： | Parasuraman Karthikeyan Pundlik Rambhau Bhagat S.Senthil Kumar |
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| 作者单位： | Organic Chemistry Division, School of Advanced Sciences, VIT University, Vellore -632 014, India |
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| 摘 要： | A variety of alkyl-arenes and cyclohexane were converted to the corresponding ketones with NaCIO as the oxidant in the presence of l-glycyl-3-methyl imidazolium chloride-copper(Ⅱ) complex.This method contains simplified product isolation and catalyst recycling,affording benzylic C-H oxidation of alkyl-arenes imparting high yield of ketones.Furthermore,complex could be reused seven times without a significant loss of its catalytic activity.
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| 关 键 词： | Copper Alkane Ionic liquid Room temperature |
| 收稿时间： | 16 February 2012 |
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