Phosphine-free cross-coupling reaction of arylboronic acids with carboxylic anhydrides or acyl chlorides in aqueous media |
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Authors: | Xin Bingwei Zhang Yuhong Cheng Kai |
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Institution: | Department of Chemistry, Zhejiang University, Hangzhou 310027, P.R. China. |
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Abstract: | The palladium acetate-catalyzed coupling reaction of aryl boronic acid with carboxylic anhydride or acyl chloride was carried out smoothly in water in the presence of poly(ethylene glycol) (PEG) or 1-butyl-3-methylimidazolium hexafluorophosphate (bmim]PF6]) to give high yields of ketones without the use of phosphine ligands. The Pd(OAc)2-H2O-bmim]PF6] catalytic system can be recovered and reused eight times with high efficiency for both carboxylic anhydride and acyl chloride. |
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