The effect of encapsulated cyanide complexes on the localization of cations in faujasite |
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Authors: | Yu G Gol’tsov L A Matkovskaya V G Il’in |
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Institution: | Yu. G. Gol’tsov, L. A. Matkovskaya and V. G. Il’in |
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Abstract: | Features of the localization of various types of cations and their distribution between the structural elements of the framework
of faujasite with encapsulated hexacyanide complexes of iron(II) and cobalt(III) were established. The content of the alkali-metal
cations in the sodalite cells is increased compared with faujasite, and the cations of the transition metals are localized
in the large cavities with the formation of Me(SII)−NC−Fe(CN)5 (Me=Cu, Co) and (NC)5Fe−CN−Me(SV)−NC−Fe(CN)5 (Me=Ni, Cu, Co) fragments.
L. V. Pisarzhevskii Institute of Physical Chemsitry, National Academy of Sciences of Ukraine, 31 Prospekt Nauki, Kiev 252039,
Ukraine. Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 35, No. 1, pp. 56–61, January–February, 1999. |
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