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Sedimentation and drying dissipative patterns of colloidal silica (305 nm in diameter) suspensions in a glass dish and a watch glass
Authors:Tsuneo Okubo  Junichi Okamoto  Akira Tsuchida
Institution:(1) Institute for Colloidal Organization, Hatoyama 3-1-112, Uji, Kyoto 611-0012, Japan;(2) Cooperative Research Center, Yamagata University, Johnan 4-3-16, Yonezawa 992-8510, Japan;(3) Department of Applied Chemistry, Gifu University, Gifu 501-1193, Japan
Abstract:Sedimentation and drying dissipative structural patterns formed in the course of drying colloidal silica spheres (305 nm in diameter) in aqueous suspension have been studied in a glass dish and a watch glass. The broad ring sedimentation patterns formed within several tenth minutes in suspension state by the convectional flow of water and colloidal spheres. The sedimentary spheres always moved by the convectional flow of water, and the broad ring patterns became sharp with time. The width of the broad rings was sensitive to the change in the room temperature and/or humidity. In other words, the patterns became sharp or vague when the room parameters decreased or increased. Colorful macroscopic drying structures were composed of a broad ring and the wave-formed patterns. Iridescent colored fine patterns formed in the solidification processes on the bases of the sedimentation patterns. Beautiful drying patterns were observed for the suspension mixtures of CS300 and NaCl, and were different from the structures of CS300 or NaCl individuals, which support the synchronous cooperative interactions between the colloidal spheres and the salt.
Keywords:Sedimentation dissipative structure  Drying dissipative structure  Colloidal silica spheres  Broad ring pattern  Wave-like pattern
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