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Synchotron radiation photoemission study of adsorbate-induced 3d core level shifts of Pd(110)
Authors:G. Comelli   M. Sastry   G. Paolucci   K. C. Prince  L. Olivi
Affiliation:

b Sincrotrone Trieste, Padriciano 99, 34012, Trieste, Italy

* Area per la Ricerca Scientifica e Tecnologica nella Provincia di Trieste, Padriciano 99, 34012, Trieste, Italy

Abstract:The surface core level shifts of Pd(110) and oxygen and CO covered Pd(110) have been measured using synchrotron radiation. The results are consistent with values predicted using a Born-Haber cycle, confirming the usefulness of this approach. The largest shift occurs for the CO covered surface, indicating that initial state charge transfer does not dominate the shifts.
Keywords:
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