New band systems of NiBr molecule in visible region |
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Authors: | R Gopal M M Joshi |
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Affiliation: | (1) Saha’s Spectroscopic Laboratory, Physics Department, Allahabad University, 211 002 Allahabad, India |
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Abstract: | Thermal emission spectrum of NiBr molecule excited by vacuum graphite tube furnace revealed the existence of ten new band sub-systems in the region λλ 5540-4720 Å which were attributed toA→X,B→X,C→X andD→X transitions. Vibrational analysis was carried out for each of the systems mentioned above.A 2 Δ has been suggested as the ground state of NiBr molecule with an electronic interval of about 533 cm?1. Transitions responsible for NiBr spectrum appear to be of the type2π–2Δ and2Δ–2Δ. |
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Keywords: | Thermal emission molecular spectra spectra of inorganic diatomic molecule transition elements |
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