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New band systems of NiBr molecule in visible region
Authors:R Gopal  M M Joshi
Affiliation:(1) Saha’s Spectroscopic Laboratory, Physics Department, Allahabad University, 211 002 Allahabad, India
Abstract:Thermal emission spectrum of NiBr molecule excited by vacuum graphite tube furnace revealed the existence of ten new band sub-systems in the region λλ 5540-4720 Å which were attributed toAX,BX,CX andDX transitions. Vibrational analysis was carried out for each of the systems mentioned above.A 2 Δ has been suggested as the ground state of NiBr molecule with an electronic interval of about 533 cm?1. Transitions responsible for NiBr spectrum appear to be of the type2π–2Δ and2Δ–2Δ.
Keywords:Thermal emission  molecular spectra  spectra of inorganic diatomic molecule  transition elements
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