Chain dynamics of bilayer n-decylammonium chloride studied by deuteron NMR spectroscopy |
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Authors: | S. Jurga V. Macho B. Hüser H. W. Spiess |
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Affiliation: | (1) Institute of Physics, A. Mickiewicz University, Grunwaldzka 6, PL-60-780 Poznan, Poland;(2) Max-Planck-Institut für Polymerforschung, Postfach 3148, W-6500 Mainz, Federal Republic of Germany |
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Abstract: | N-decylammonium chloride is a polymorphic solid which exhibits a variety of layered phases. The molecular dynamics and phase transitions in these phases have been studied using2H NMR of selectively deuterated n-decylammonium in the chain positions 1 and 6 and in the ammonium group. Measurements were performed over the temperature range of the interdigitated phase I, the non-interdigitated monoclinic phase , the tetragonal phase , and the monotropic phase , obtained upon cooling the sample from the -phase. In phase I, below 321 K, the hydrocarbon chain is rigid except for ND3 rotation about its own symmetry axis. In phase , between 321 K and 325 K, a fast motion of the hydrocarbon chains is assigned to an exchange between two pairwise nonequivalent positions. The chains are slightly tilted in this phase. In phase above 325 K the chains rotate freely around their long axes experiencing additional transgauche conformational dynamics. In the non-interdigitated phase the spectra can be interpreted by assuming a reorientation between two variously occupied potential wells about the axis determined by the C-N bond, which is believed to be parallel to the normal bilayer axis. |
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