New cationic and anionic tetracoordinate nickel(I) complexes |
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| Authors: | Manuel Gómez Pascual Royo |
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| Institution: | (1) Departamento de Quimica Inorgánica, Facultad de Ciencias, Universidad de Alcalá de Henares, Alcalá de Henares, Madrid, Spain |
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| Abstract: | Summary The preparation, structural study and chemical behaviour of new cationic, monoanionic and dianionic tetracoordinate nickel(I) complexes of the types: NiL4]BPh4] (L=PPh3, AsPh3 or SbPh3), PR4]NiX2L2] (X=Cl, Br or I; L=PPh3, AsPh3 or SbPh3 and PR4]+=PPh4, Ph3PCH2Ph or Ph3PEt) and PR4]2NiX3L] (X=Cl, Br or I; L=PPh3 and PR4]+=PPh4 or PPh3CH2Ph) are described. |
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