The preparation, crystal structure and properties of a mixed-ligand copper(I) complex [CuI(PPh3)(DPPZ)]·DMF |
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| Authors: | Yu-Jun Shi Shu-Jian Chen Bin Huang Xue-Tai Chen Yong Zhang Xiao-Zeng You |
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| Affiliation: | State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing 210093, People's Republic of China |
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| Abstract: | The mixed ligand mononuclear copper(I) complex of formula [CuI(PPh3)(DPPZ)]·DMF (DPPZ=dipyrido[3,2,-a:2′,3′-c]phenazine) has been synthesized and has been characterized by single-crystal X-ray diffraction method, FT-IR spectrum, the electrospray ionization mass spectrum and the thermogravimetric analysis. The pairwise π–π stacking between DPPZ ligands exists through the crystal lattice. |
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| Keywords: | Copper(I) complex Crystal structure Electrospray ionization mass spectrum DPPZ |
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