| 6，6－二苯基富烯在Cp_2TiCl_2－i－prMgBr催化下的加氢反应 |
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| 引用本文： | 贺峥杰,陈寿山.6，6－二苯基富烯在Cp_2TiCl_2－i－prMgBr催化下的加氢反应[J].高等学校化学学报,1994(5). |
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| 作者姓名： | 贺峥杰 陈寿山 |
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| 作者单位： | 南开大学元素有机化学研究所 |
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| 摘 要： | ６，６－二苯基富烯在Ｃｐ_２ＴｉＣｌ_２－ｉ－ｐｒＭｇＢｒ催化下的加氢反应贺峥杰，陈寿山（南开大学元素有机化学研究所，天津，３０００７１）关键词富烯，催化氢化，异构化在温和条件和氢气氛下，Ｃｐ２ＴｉＣｌ２与ｉ－ｐｒＭｇＢｒ组成的低价态钛催化体系对１，５...
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| 关 键 词： | 富烯，催化氢化，异构化 |
Catalytic Hydrogenation of 6,6-Diphenylfulvene in the Presence of Cp_2TiCl_2-i-PrMgBr |
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| HE Zheng-Jie,CHEN Shou-Shan.Catalytic Hydrogenation of 6,6-Diphenylfulvene in the Presence of Cp_2TiCl_2-i-PrMgBr[J].Chemical Research In Chinese Universities,1994(5). |
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| Authors: | HE Zheng-Jie CHEN Shou-Shan |
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| Abstract: | In this paper,we described catalytic hydrogenation of 6,6-diphenylfulvene in the presence of Cp2TiCl2-i-PrMgBr system under mild conditions,It was found that the low valent titanium catalyst from Cp2TiCl2 and i-prMgBr has a good activity for hydrogenation of the fulvene,and that the catalyst is active for isomerization of adduct hydrogen product.It was also found that there is an obvious gradient velocity of hydrogenation in the reaction. |
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| Keywords: | Diphenylfulvene Catalytic hydrogenation Isomerization |
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