Core electron spectroscopy of water solutions |
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| Institution: | 1. Div. Inorganic Chemistry/Dept. Chemistry (Ångström), Uppsala University, Box 538, SE-751 21 Uppsala, Sweden;2. Helmholtz Zentrum Berlin für Materialien und Energie GmbH, Albert-Einstein-Str. 15, Berlin 12489, Germany;1. Jožef Stefan Institute, P.O. Box 3000, SI-1001 Ljubljana, Slovenia;2. University of Ljubljana, Faculty of Mathematics and Physics, Jadranska 21, SI-1000 Ljubljana, Slovenia;3. Research Centre for Molecular Materials, University of Oulu, P.O. Box 3000, FIN-90014 Oulu, Finland;4. Sorbonne Universités, UPMC Univ Paris 06, UMR 7614, Laboratoire de Chimie Physique Matière et Rayonnement, F-75005 Paris, France;5. CNRS, UMR 7614, Laboratoire de Chimie Physique Matière et Rayonnement, F-75005 Paris, France;6. Department of Physics and Astronomy, Uppsala University, P.O. Box 516, 75120 Uppsala, Sweden;1. Centre for Theoretical and Computational Chemistry, Department of Chemistry, University of Tromsø, The Arctic University of Norway, N-9037 Tromsø, Norway;2. Max-Planck-Institute for Plasma Physics, Boltzmannstr. 2, 85748 Garching, Germany;3. Leibniz Institute of Surface Modification, Permoserstr. 15, 04318 Leipzig, Germany;4. Max-Planck-Institute for Plasma Physics, Wendelsteinstr. 1, 14791 Greifswald, Germany;1. Instituto de Física, Universidade Federal do Rio de Janeiro, PO 68528, 21941-972 Rio de Janeiro,RJ, Brazil;2. Instituto de Química Universidade Federal do Rio de Janeiro, Ilha do Fundão, CT, Bloco A, Rio de Janeiro, RJ, CEP 21941-909, Brazil;3. In memorian |
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| Abstract: | O1s spectra from water in glycol, dimethylformamide and LiCl solutions have been recorded. The liquid/vapour shift is found to differ between the three solutions and from that measured for the pure organic solvents. The correlation of the shifts with molecular size and polarizability is discussed. The O1s binding energy for H2O in the LiCl solution is measured to be 538.0 eV. From the liquid/vapour shift in this solution an estimate is obtained of. the electronic polarization contribution to the solvation energy of the K+ ion in water. |
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