| 一维链状锰(Ⅱ)三氮唑配合物的合成，结构与磁性质(英) |
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| 引用本文： | 刘正,周建豪,李一志,宋友,陈学太. 一维链状锰(Ⅱ)三氮唑配合物的合成，结构与磁性质(英)[J]. 无机化学学报, 2005, 21(10): 1601-1604 |
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| 作者姓名： | 刘正 周建豪 李一志 宋友 陈学太 |
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| 作者单位： | 南京大学配位化学研究所,配位化学国家重点实验室,南京,210093 |
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| 基金项目： | 南京大学分析测试基金资助项目 |
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| 摘 要： | A novel one-dimensional chain manganese(Ⅱ) compound [Mn(trz)2Cl][phthH], (trz=1,2,4-triazole, phthH=hydrogen phthalate), 1, was synthesized and structurally characterized. It crystallizes in monoclinic system, space group P2 /c with a=1.381 1(11) nm, b=0.815 5(7) nm, c=0.735 4(6) nm, β=94.667(15)°, V=0.825 5(12) nm3. It consists of one dimensional cationic manganese(Ⅱ) chain and uncoordinated hydrogen phthalate anions. The manganese(Ⅱ) ions are bridged with two 1,2,4-traizoles and one chloride anion along the cationic chain, in which the weak antiferromagnetic exchange occurs between manganese(Ⅱ) atoms. CCDC: 267461.
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| 关 键 词： | 锰配合物； 三氮唑； 一维链状； 磁性质 |
| 文章编号： | 1001-4861(2005)10-1601-04 |
| 收稿时间： | 2005-04-05 |
| 修稿时间： | 2005-08-04 |
Synthesis, Structure and Magnetic Property of a One-Dimensional Chain Manganese Compound with 1,2,4-Triazole |
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| LIU Zheng,ZHOU Jian-Hao,LI Yi-Zhi,SONG You and CHEN Xue-Tai. Synthesis, Structure and Magnetic Property of a One-Dimensional Chain Manganese Compound with 1,2,4-Triazole[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(10): 1601-1604 |
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| Authors: | LIU Zheng ZHOU Jian-Hao LI Yi-Zhi SONG You CHEN Xue-Tai |
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| Affiliation: | Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 |
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| Abstract: | A novel one-dimensional chain manganese(Ⅱ) compound [Mn(trz)2Cl][phthH], (trz=1,2,4-triazole, phthH=hydrogen phthalate), 1, was synthesized and structurally characterized. It crystallizes in monoclinic system, space group P2/c with a=1.381 1(11) nm, b=0.815 5(7) nm, c=0.735 4(6) nm, β=94.667 (15)°, V=0.825 5(12) nm3. It consists of one dimensional cationic manganese(Ⅱ) chain and uncoordinated hydrogen phthalate anions. The manganese(Ⅱ) ions are bridged with two 1,2,4-traizoles and one chloride anion along the cationic chain, in which the weak antiferromagnetic exchange occurs between manganese(Ⅱ) atoms. CCDC: 267461. |
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| Keywords: | manganese complex triazole one-dimensional magnetic property |
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