Synthesis and Properties of meso-Monophenyltetrabenzoporphine and Its Zinc Complex |
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| Authors: | Galanin N. E. Kudrik E. V. Shaposhnikov G. P. |
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| Affiliation: | (1) Ivanovo State University of Chemical Engineering, Ivanovo, Russia |
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| Abstract: | meso-Monophenyltetrabenzoporphine and its zinc complex were synthesized starting from 3-(3-oxo-2,3-dihydro-1H-isoindol-1-ylidenemethyl)-1H-isoindol-1-one. The effect of unsymmetrical meso-substitution on physical and spectral properties of the products is discussed. The results of quantum-chemical calculations suggest spatial distortion of the porphyrin macroring. |
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