Analysis of the thermophysical properties of some rare-earth hydroxides through crystal field effects |
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| Authors: | S. Dasgupta M. Saha D. Ghosh |
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| Affiliation: | Magnetism Department, Indian Association for the Cultivation of Science Jadavpur, Calcutta 700032, India |
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| Abstract: | A crystal field analysis of the experimental results on the magnetic susceptibilities and their anisotropies in Ho(OH)3 and Tb(OH)3 was made with a view to resolve the previous anomalies observed in the results of specific heat studies. A pronounced thermal effect on lattice specific heat has been observed in Ho(OH)3 but not in Tb(OH)3. For Er(OH)3, the total specific heat was calculated with reasonable assumptions over a wide temperature range, but no experimental data are yet available for comparison. |
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