Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane-borane adduct |
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| Authors: | Spies Patrick Erker Gerhard Kehr Gerald Bergander Klaus Fröhlich Roland Grimme Stefan Stephan Douglas W |
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| Affiliation: | Organisch-Chemisches Institut, Universit?t Münster, Corrensstrasse 40, D-48149 Münster, Germany. |
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| Abstract: | A four-membered cyclic intramolecular phosphane-borane adduct activates dihydrogen to yield the respective ethylene-bridged zwitterionic phosphonium-hydridoborate system, which reduces benzaldehyde. |
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