Vibrational spectra of 1-chloro-2-methylpropane and 1-chloro-2,2-dimethylpropane |
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Authors: | G.A. Crowder Way-Yu Lin |
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Affiliation: | Department of Chemistry, West Texas State University, Canyon, Texas 79016 U.S.A. |
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Abstract: | Infrared and Raman spectra are obtained for 1-chloro-2-methylpropane and 1-chloro-2,2-dimethylpropane. The former compound exists as a mixture of PC and PH' conformers in the liquid and unannealed solid states, but only the PC conformer is present in the crystalline solid. Vibrational assignments are made for both conformers of 1-chloro-2-methylpropane and for 1-chloro-2,2-dimethylpropane with the aid of normal coordinate calculations. |
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