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35-Cl nuclear quadrupole resonance spectra in diazepam and its 1:1 complex with chloral hydrate
Authors:Colette Brisson  Marcel Durand  Gérard Jugie  Maurice Pasdeloup
Affiliation:Laboratoire de Chimie de Coordination du C.N.R.S., associé à l''Université Paul-Sabatier, 205 route de Narbonne, 31400 ToulouseFrance
Abstract:The 35-Cl NQR spectra of diazepam and some of its related compounds are reported; they yield information about the hydrogen bonded complex that diazepam forms with chloral hydrate. The results reflect large changes in electron distribution at the CCl3 group while the diazepam chlorine at the 7 position remains almost unaffected.
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