Laser-microwave double-resonance spectroscopy in CF3I with four CO2-laser lines |
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Authors: | Franz Kohler Harold Jones H.D. Rudolph |
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Affiliation: | Department of Chemistry, University of Ulm, D-7900 Ulm, West Germany |
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Abstract: | Double-resonance effects produced by three CO2-laser lines, the 9.4-μmR(12),R(14), and R(18), have been newly observed. From an analysis of the observed laser-induced changes in intensity of various microwave transitions, the infrared transitions which were accidentally coincident with these three laser lines were determined. In every case an exact rotational assignment of the infrared transition was possible, but in some cases the assignment of the vibrational band involved was difficult. When the previously discussed (l) effects produced by the R(16) laser line are included these four consecutive laser lines pump a total of seven infrared transitions of CF3I. It appears that all seven transitions belong to different fundamental, combination, and hot bands. |
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