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A functional applied material on recognition of metal ion zinc based on the double azine compound
Authors:Taibao Wei  Guoyan Liang  Xiaopeng Chen  Jin Qi  Qi Lin  Youming Zhang  Hong Yao
Affiliation:1. Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education, Gansu 730070, PR China;2. Key Laboratory of Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, PR China
Abstract:A colorimetric and fluorescent probe L has been designed and synthesized, which bearing the double azine moiety and showing a detection limit of 2.725 × 10?7 M towards Zn2+. Based on the basic recognition mechanism of ESIPT and CHEF effect, the L has high selectivity and sensitivity to only Zn2+ (not Fe3+, Hg2+, Ag+, Ca2+, Co2+, Ni2+, Cd2+, Pb2+, Cr3+, and Mg2+) within the physiological pH range (pH = 7.0–8.4) and showed a fluorescence switch. Moreover, this detection progress occured in the DMSO/H2O ~ HEPES buffer (80/20, v/v; pH 7.23) solution which can conveniently used on test strip.
Keywords:Fluorescent probe  Double azine  Fluorescence switch  Test strip
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