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多巴胺和L-精氨酸制备超轻氮掺杂石墨烯气凝胶吸油性能的研究
引用本文:多巴胺和L-精氨酸制备超轻氮掺杂石墨烯气凝胶吸油性能的研究.多巴胺和L-精氨酸制备超轻氮掺杂石墨烯气凝胶吸油性能的研究[J].燃料化学学报,2017,45(10):1230-1235.
作者姓名:多巴胺和L-精氨酸制备超轻氮掺杂石墨烯气凝胶吸油性能的研究
作者单位:1. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China; 2. Qingdao Institute of Textile Fiber Supervision and Inspection, Qingdao 266061, China
摘    要:采用水热法制备了超轻氮掺杂石墨烯气凝胶。分析表征结果表明,多巴胺不仅为还原剂而且提供氮源,石墨烯溶液前躯体的pH值对水热法制备超轻氮掺杂石墨烯气凝胶很大的影响,通过调节多巴胺和L-精氨酸在石墨烯溶液前躯体的浓度,可制备密度为2.54 mg/cm3超轻氮掺杂石墨烯气凝胶,由于氮掺杂、低密度和大的比表面积,超轻氮掺杂石墨烯气凝胶对各种油品都有良好的吸附性能。

关 键 词:石墨烯气凝胶  多巴胺  L-精氨酸  油品吸附  氮掺杂  
收稿时间:11 May 2017

Dopamine and L-arginine tailored fabrication of ultralight nitrogen-doped graphene aerogels for oil spill treatment
Xue YU,Pei-wen WU,You-chang LIU,Liang WANG,Li-juan FENG,Chun-hu LI.Dopamine and L-arginine tailored fabrication of ultralight nitrogen-doped graphene aerogels for oil spill treatment[J].Journal of Fuel Chemistry and Technology,2017,45(10):1230-1235.
Authors:Xue YU  Pei-wen WU  You-chang LIU  Liang WANG  Li-juan FENG  Chun-hu LI
Institution:1. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China;2. Qingdao Institute of Textile Fiber Supervision and Inspection, Qingdao 266061, China
Abstract:Ultralight and nitrogen doped graphene aerogels (UNGAS) are developed by a hydrothermal method in the presence of graphene, dopamine (DA) and L-arginine. Analysis shows that DA can functionalize the graphene surface and also embed nitrogen atoms onto the graphene sheets upon pyrolysis, and the values of pH on the hydrothermal fabrication of UNGAS have great influence on the formation of UNGAS. By adjusting the amount of L-arginine and dopamine in the precursor mixture, UNGAS with a density as low as 2.54 mg/cm3 can be prepared. The UNGAS show high absorption capacity for various oils due to low density, N doping and large surface area.
Keywords:graphene aerogel  dopamine  L-arginine  oil absorption  nanocomposites
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