Cationic Pd(II)-catalyzed arylative cyclization of 1,6-enynes with arylboronic acids |
| |
| Authors: | Kun Shen Xiuling Han Xiyan Lu Zhiyong Hu |
| |
| Affiliation: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China |
| |
| Abstract: | A cationic Pd(II)-catalyzed redox neutral arylative cyclization of enynes by using β-acetoxy elimination as the quenching step has been developed. The reaction offers an efficient method to access a variety of carbocycles and N-heterocycles bearing an exocyclic double bond. |
| |
| Keywords: | Cationic palladium 1,6-Enyne Arylboronic acid Carbopalladation β-Heteroatom elimination |
| 本文献已被 ScienceDirect 等数据库收录！ |
