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Green and mild laccase-catalyzed aerobic oxidative coupling of benzenediol derivatives with various sodium benzenesulfinates
Authors:Davood Habibi  Abdollah Rahimi  Amin Rostami  Sirvan Moradi
Institution:1. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran;2. Department of Chemistry, Faculty of Sciences, University of Kurdistan, Sanandaj 6617715143, Iran
Abstract:The oxidative coupling reaction between hydroquinone or catechols and various sodium benzenesulfinates was investigated using the laccase from Trametes versicolor, in the presence of O2 in a phosphate buffer solution at room temperature to afford sulfonyl benzenediols in 75–95% yield.
Keywords:Laccase enzyme  Catechol  Sodium benzenesulfinates  Phosphate buffer solution  Oxidative coupling  Sulfonyl benzenediols
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