Catalytic Synthesis of n-Butyraldehyde 1,2-propanediol Acetal over H4SiW12O40-PAn |
| |
Authors: | Shuijin Yang Shaomin Shi Xieqing Yu |
| |
Institution: | (1) Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi, Hubei, 435002, China;(2) College of Chemistry, Central China Normal University, Wuhan, Hubei, 430079, China |
| |
Abstract: | A new environmentally friendly catalyst, H4SiW12O40-polyaniline (PAn), was prepared, and n-butyraldehyde 1,2-propanediol acetal was synthesized from n-butyraldehyde and 1,2-propanediol in the presence of H4SiW12O40-PAn. The influence factors of the synthesis were discussed, and the best reaction conditions were found: the molar ratio
of n-butyraldehyde to 1,2-propanediol is 1:1.5, the amount of catalyst used is 1.2% of feed stock, and the reaction time is 1.0
h. H4SiW12O40-PAn is an excellent catalyst for synthesizing n-butyraldehyde 1,2-propanediol acetal, and the yield can reach more than 95.2%.
*Translated from Journal of Central China Normal University (Natural Sciences Edition), 2005, 39(9) (in Chinese), 2004, 28(4) (in Chinese) |
| |
Keywords: | n-butyraldehyde 1 2-propanediol acetal 12-tungstosilicic acid polyaniline catalyst acetalation |
本文献已被 万方数据 SpringerLink 等数据库收录! |
|