A general palladium-catalyzed coupling of aryl bromides/triflates and thiols |
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| Authors: | Itoh Takahiro Mase Toshiaki |
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| Institution: | Process Research, Process R & D, Banyu Pharmaceutical Co. Ltd., 9-1 Kamimutsuna 3-Chome, Okazaki, Aichi 444-0858, Japan. takahiro_itoh@merck.com |
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| Abstract: | We have developed an efficient palladium-catalyzed carbon-sulfur bond formation reaction of aryl bromides, triflates, and activated aryl chloride. Using this protocol, we have shown tolerance to a wide variety of aryl thiols and alkyl thiols that can also be used as sulfide equivalents. reaction: see text] |
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