Reactions of diisobutyl- and diethylaluminum hydrides with α-acetylenes |
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| Authors: | V V Gavrilenko B A Palei L I Zakharkin |
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| Institution: | (1) Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR |
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| Abstract: | Conclusions To obtain Al vinyl compounds R2A1CH=CHR' by reacting R2AlH with HC=CR', we must use weakly acid acetylenes (alkyl acetylenes) and perform the reaction in aliphatic hydrocarbons at a low temperature in excess acetylene.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 910–912, April, 1968. |
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